Orthomercurated and cycloaurated derivatives of the iminophosphorane Ph3P NPh

Ortho-lithiation of Ph3P NPh followed by reaction with HgCl2 gave good yields of [Hg{C6H4(PPh2 NPh)-2}Cl], 3, which was characterised spectroscopically and by an X-ray crystal structure determination. This is an isomer of the product of direct mercuration of Ph3P NPh which occurs on the N-bonded phenyl ring [J. Vicente, J.A. Abad, R. Clemente, J. Lopez-Serrano, M.C. Ramirez de Arellano, P.G. Jones, D. Bautista, Organometallics, 22 (2003) 4248]. Transmetallation of 3 with [AuCl4]− gave the corresponding cycloaurated complex [Au{κ2-C,N-C6H4(PPh2 NPh)-2}Cl2], with a five-membered metallocyclic ring incorporating four different elements

A COMPUTER PROGRAM FOR THE KINETIC ANALYSIS OF A LINK-SEGMENT MODEL

The computer program LINK has been created to aid the biomechanics instructor in the teaching and demonstration of kinetic analysis of a knee joint link-segment model. Written in the BASIC computer programming language, this program is designed to be a step-by-step demonstration tool complete with geometric diagrams, discussion of pertinent terms, and mastery tests. Input values are based upon anthropometric measurements, force values recorded from an isokinetic dynamometer (Cybex), and corresponding knee angles. Preset values may be selected for demonstration, or the user may input hisher own data. The output is calculated values of force, torque, and power (for the knee joint angles utilized). Specific geometry for these calculations are based upon the anthropometric measures. This computer program is written to be used with all IBM compatible microcomputers

Spanning forest polynomials and the transcendental weight of Feynman graphs

We give combinatorial criteria for predicting the transcendental weight of Feynman integrals of certain graphs in $\phi^4$ theory. By studying spanning forest polynomials, we obtain operations on graphs which are weight-preserving, and a list of subgraphs which induce a drop in the transcendental weight.Comment: 30 page

Extension of random-phase approximation preserving energy weighted sum rules: an application to a 3-level Lipkin model

A limitation common to all extensions of random-phase approximation including only particle-hole configurations is that they violate to some extent the energy weighted sum rules. Considering one such extension, the improved RPA (IRPA), already used to study the electronic properties of metallic clusters, we show how it can be generalized in order to eliminate this drawback. This is achieved by enlarging the configuration space, including also elementary excitations corresponding to the annihilation of a particle (hole) and the creation of another particle (hole) on the correlated ground state. The approach is tested within a solvable 3-level model.Comment: 2 figure

Temperature dependence of the nuclear symmetry energy

We have studied the properties of A=54 and A=64 isobars at temperatures T \leq 2 MeV via Monte Carlo shell model calculations with two different residual interactions. In accord with empirical indications, we find that the symmetry energy coefficient, b_{sym}, is independent of temperature to within 0.6 MeV for T \leq 1 MeV. This is in contrast to a recent suggestion of a 2.5 MeV increase of b_{sym} for this temperature, which would have significantly altered the supernova explosion scenario.Comment: 7 pages, including 2 figures, Caltech preprint MAP-17

Synchronization Based Approach for Estimating All Model Parameters of Chaotic Systems

The problem of dynamic estimation of all parameters of a model representing chaotic and hyperchaotic systems using information from a scalar measured output is solved. The variational calculus based method is robust in the presence of noise, enables online estimation of the parameters and is also able to rapidly track changes in operating parameters of the experimental system. The method is demonstrated using the Lorenz, Rossler chaos and hyperchaos models. Its possible application in decoding communications using chaos is discussed.Comment: 13 pages, 4 figure

Maternal obesity is associated with the formation of small dense LDL and hypoadiponectinemia in the third trimester

Context: Maternal obesity is associated with high plasma triglyceride, poor vascular function, and an increased risk for pregnancy complications. In normal-weight pregnant women, higher triglyceride is associated with increased small, dense low-density lipoprotein (LDL). Hypothesis: In obese pregnancy, increased plasma triglyceride concentrations result in triglyceride enrichment of very low-density lipoprotein-1 particles and formation of small dense LDL via lipoprotein lipase. Design: Women (n = 55) of body mass index of 18–46 kg/m2 were sampled longitudinally at 12, 26, and 35 weeks' gestation and 4 months postnatally. Setting: Women were recruited at hospital antenatal appointments, and study visits were in a clinical research suite. Outcome Measures: Plasma concentrations of lipids, triglyceride-rich lipoproteins, lipoprotein lipase mass, estradiol, steroid hormone binding globulin, insulin, glucose, leptin, and adiponectin were determined. Results: Obese women commenced pregnancy with higher plasma triglyceride, reached the same maximum, and then returned to higher postnatal levels than normal-weight women. Estradiol response to pregnancy (trimester 1–3 incremental area under the curve) was positively associated with plasma triglyceride response (r2 adjusted 25%, P < .001). In the third trimester, the proportion of small, dense LDL was 2-fold higher in obese women than normal-weight women [mean (SD) 40.7 (18.8) vs 21.9 (10.9)%, P = .014], and 35% of obese, 14% of overweight, and none of the normal-weight women displayed an atherogenic LDL subfraction phenotype. The small, dense LDL mass response to pregnancy was inversely associated with adiponectin response (17%, P = .013). Conclusions: Maternal obesity is associated with an atherogenic LDL subfraction phenotype and may provide a mechanistic link to poor vascular function and adverse pregnancy outcome